All is sorted now, running and recording properly. I found messing with the muxes was problematic, but then found that Linux TV has more up to date muxes at:
> https://linuxtv.org/downloads/dtv-scan-tables/dtv-scan-tables-LATEST.tar.bz2
On the RPi, unlike a Debian 9 install, the tables are located at:
* /usr/share/dvb/
I replaced the whole of the dvb-t directory although I noticed that a new install of TVHeadEnd, on the RPI, had a more up-to-date Mux for Mendip-UK, including the missing channel 35 (edit - 65!) , 586 MHz.
Hope this is useful to some RPi user, left behind by frequency changes. Our next frequency change was due on June 22nd, but has been postponed until a later date, not yet known.