See subscriptions tab.
1 tuner can record all services on this frequency (on picture 690mhz)
there can be few tv an radio services.
You can record an watch whatever is broadcasted on this frequency, but if need second one, take second tuner or better dual tuner.
See configuration>dvb input>services (sorted by MUX and from drop-down menu sorted in groups)
Equal situation on TV, you can watch PiP only on channels on same frequency (transponder/mux) or on another input (AV/SVideo/Scart/HDMI).